Nickel Chloride
MATERIAL SAFETY DATA SHEET
I. PRODUCT IDENTIFICATION
Manufacturer/Supplier:
ESPI Metals
1050 Benson Way, Ashland, OR 97520
Toll Free (800) 638-2581 * Fax (541) 488-8313
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Product Name: Nickel Chloride
Formula: NiCl2
CAS Number: 7718-54-9
II. HAZARDOUS INGREDIENTS
Hazardous Component: Nickel Chloride
Percent (%): 0-100
OSHA/PEL: 1 mg(Ni)/m3
ACGIH/TLV: 0.1 mg(Ni)/m3 (soluble compounds)
HMIS Rating:
Health: 4
Flammability: 0
Reactivity: 0
III. PHYSICAL DATA
Boiling Point: 973 oC (sublimes)
Melting Point: 1001 oC
Specific Gravity: 3.55 g/cc
Solubility in H2O: Soluble
Appearance and Odor: Yellow powder, no odor.
IV. FIRE AND EXPLOSION HAZARDS DATA
Flash Point: N/A
Flammability: Non-flammable
Autoignition Temperature: N/A
Explosive Limits: Upper: N/A Lower: N/A
Extinguishing Media: Use suitable extinguishing media for surrounding material and type of fire.
Special Firefighting Procedures: Firefighters must wear full face, self-contained breathing apparatus and full protective clothing to prevent contact with skin and eyes.
Unusual Fire & Explosion: When heated to decomposition, this material may emit toxic fumes of chlorine.
V. HEALTH HAZARD INFORMATION
Effects of Exposure:
To the best of our knowledge the chemical, physical and toxicological properties of nickel chloride have not been thoroughly investigated and recorded.
Nickel is a confirmed carcinogen with experimental carcinogenic, neoplastigenic, tumorigenic and teratogenic data. Poison by ingestion, intratracheal, intraperitoneal, subcutaneous and intravenous routes. An experimental teratogen. Ingestion of soluble salts causes nausea, vomiting and diarrhea. Hypersensitivity to nickel is common and can cause allergic contact dermatitis, pulmonary asthma, conjunctivitis and inflammatory reactions around nickel containing medical implants and prosthesis.
Chlorides toxicity varies widely. Sodium chloride (table salt) has very low toxicity, while carbonyl chloride (phosgene) is lethal in small doses. (Sax, Dangerous Properties of Industrial Materials)
Acute Effects:
Inhalation: Severe irritant and corrosive. May cause irritation to the upper respiratory tract, mucous membranes and nasal cavities. May cause pulmonary asthma attacks.
Ingestion: Severe irritant and corrosive. Large doses may cause intestinal disorders, convulsions and asphyxia.
Skin: Severe irritant and corrosive.
Eye: Severe irritant and corrosive.
Chronic Effects:
Inhalation: Prolonged or repeated inhalation may cause pneomitis.
Ingestion: May cause nickel toxicity.
Skin: May sensitize the skin (nickel itch). May cause allergic dermatitis, eczematous dermatitis and may be accompanied a week later with superficial skin ulcers, which may discharge and become crusted.
Eye: May cause conjunctivitis.
Target Organs: May affect the nasal cavities, respiratory system, lungs, blood and skin.
Medical Conditions Generally Aggravated by Exposure: Pre-existing respiratory disorders, pulmonary functions, asthma and skin disorders.
Carcinogenicity: NTP: Yes IARC: Yes OSHA: Yes
EMERGENCY AND FIRST AID PROCEDURES:
INHALATION: Remove to fresh air, keep warm and quiet, give oxygen if breathing is difficult and seek medical attention immediately.
INGESTION: Do not induce vomiting. Seek medical attention immediately.
SKIN: Remove contaminated clothing, brush material off skin, wash affected area with soap and water. Seek medical attention immediately.
EYE: Flush eyes with lukewarm water, including under upper and lower eyelids, for at least 15 minutes. Seek medical attention immediately.
VI. REACTIVITY DATA
Stability: Stable
Conditions to Avoid: Water/moisture
Incompatibility (Material to Avoid): Water/moisture, oxidizing agents.
Hazardous Decomposition Products: Fumes of chlorine, hydrogen chloride.
Hazardous Polymerization: Will not occur
VII. SPILL OR LEAK PROCEDURES
Steps to Be Taken in Case Material Is Released or Spilled: Wear appropriate respiratory and protective equipment specified in section VIII. Isolate spill area and provide ventilation. Sweep up or vacuum up using a high efficiency particulate absolute (HEPA) air filter and place in a container for proper disposal. Take care not to raise dust.
Waste Disposal Method: Dispose of in accordance with applicable Federal, State and Local Regulations.
VIII. SPECIAL PROTECTION INFORMATION
Respiratory Protection: Wear NIOSH-approved dust-mist-fume cartridge respirator.
Ventilation: Handle in a dry, controlled environment. Handle in an inert gas such as argon. Use local exhaust to maintain below recommended TLV levels. General exhaust is not recommended.
Protective Gloves: Rubber gloves
Eye Protection: Safety goggles
Other Protective Clothing or Equipment: Wear protective clothing to prevent contamination of skin and clothes.
IX. SPECIAL PRECAUTIONS
Precautions to Be Taken in Handling and Storage: Store in tightly closed containers in a cool, dry place. Wash hands and face thoroughly after handling and before eating.
Other Precautions: Nickel chloride is hygroscopic. Handle and store in a controlled environment and an inert gas such as argon.
Work Practices: Implement engineering and work practice controls to reduce and maintain concentration of exposure at low levels. Use good housekeeping and sanitation practices. Do not use tobacco or food in work area. Wash thoroughly before eating and smoking. Do not blow dust off clothing or skin with compressed air. Maintain eyewash capable of sustained flushing, safety drench shower and facilities for washing.
DOT Regulations:
Hazard Class: 8
Identification Number: UN1759
Packing Group: II
Proper Shipping Name: Corrosive solids, n.o.s., (Nickel chloride)
The above information is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide. ESPI shall not be held liable for any damage resulting from handling or from contact with the above product.
Prepared by: S. Dierks
Dated: April 2007
ALLOYS 
