MATERIAL SAFETY DATA SHEET




I. PRODUCT IDENTIFICATION


Manufacturer/Supplier:

ESPI Metals

1050 Benson Way, Ashland, OR 97520

Toll Free (800) 638-2581 * Fax (541) 488-8313

E-Mail: sales@espimetals.com


Trade Name:      Monel

Synonym:           Nickel Alloy



II. HAZARDOUS INGREDIENTS

 

                                                                                      ACGIH-TLV                    OSHA-

Material                            CAS#                                 mg/m3                               PEL mg/m3

Nickel                                7440-02-0                          1.0                                      1.0

Copper                               7444-50-8                          0.2 (fume)                          0.1 (fume)

Iron                                    7439-89-6                          5.0 (fume)                          10.0 (fume)

Manganese                         7439-96-5                          1.0 (fume)                          5.0

Carbon                               7440-44-0                          3.5                                      3.5

Titanium                            7440-32-6                          5                                         1.5

Aluminum                         7429-90-5                          5.0 (fume)                          5 mg/m3 - metal dust

Silicon                               7440-21-3                          10.0                                    None



III. PHYSICAL DATA


Boiling Point 760 mm Hg:             N/A

Melting Point:                                 N/A

Specific Gravity:                             Approx. 8.4 - 8.8 g/cc

Vapor Density:                               N/A

% Volatiles by Weight:                  N/A

Solubility in H2O:                           N/A

Appearance and Odor:                  Metallic solid, no odor



IV. FIRE AND EXPLOSION HAZARDS DATA


Flash Point: N/A

Autoignition Temperature: N/A

Explosive Limits: Upper: N/A     Lower: N/A


Extinguishing Media: Use suitable extinguishing media for surrounding material and type of fire.

Special Firefighting Procedures: Firefighters must wear full face, self-contained breathing apparatus with full protective clothing to prevent contact with skin and eyes.

Unusual Fire and Explosive Hazard: None



V. HEALTH HAZARD INFORMATION


Effects of Exposure:


We do not consider this product in the form it is sold to constitute a physical hazard or a health hazard. Subsequent operations such as abrading, melting, welding, cutting or processing in any other fashion may produce potentially hazardous dust or fumes which can be inhaled, swallowed, or come in contact with the skin or eyes.



No toxic effects would be expected from exposure to the solid form of this metal. Prolonged repeated exposure to fumes or dusts generated during heating, cutting, brazing or welding may or may not cause adverse health effects associated with the listed constituents in excess of OSHA permissible exposure limits.


Chronic Effects:


There are no adverse effects from the product in it’s solid form. Adverse effects may or may not result from long-term (chronic) exposure to dust, fume, gases, etc., that occur by way of subsequent operations on the product. Some studies would associate one (or more) of the constituents (per Section II) with the potential for neurologic, pulmonary, respiratory, skin or other disease. Chromium, cobalt and nickel in various chemical compounds have been identified as suspect human carcinogens by the IARC, NTP Annual Report. We believe there are no reliable scientific studies which show that workers exposed to operations upon this alloy suffer increased incidence of lung cancer or other disease because of their exposure to the forms of chromium, nickel or their elements in this product.


Important: Determine actual exposure by industrial hygienic monitoring.

Possible Signs and Symptoms of exposure to Dust, Welding Fume and Gases: Short Term Exposure: Metallic Taste, nausea, tightness of chest, fever, irritation of eyes, nose, throat and skin, loss of consciousness/death due to welding gases or lack of oxygen.

Primary Routes of Entry: Inhalation, Eye Contact, Skin Contact, Ingestion.

Medical Conditions Generally Aggravated by Exposure: Aggravation of pre-existing respiratory or allergic conditions may occur in some workers.


EMERGENCY AND FIRST AID PROCEDURES:


INHALATION: Remove to fresh air, keep warm and quiet, give oxygen if breathing is difficult, seek medical attention.

INGESTION: Seek medical help if large quantities of material have been ingested.

SKIN: Remove any contaminated clothing, brush material off of skin, wash carefully with soap and water.

EYES: Flush with copious amounts of water for 15 minutes, get medical attention.



VI. REACTIVITY DATA


Stability: Stable

Conditions to Avoid: None known

Incompatibility (Material to Avoid): Reacts with strong acids to generate hydrogen gas and may produce hexavalent chromium.

Hazardous Decomposition Products: Metallic oxides

Hazardous Polymerization: Will not occur



VII. SPILL OR LEAK PROCEDURES


Steps to be Taken in Case Material is Released or Spilled: Sweep up and place in a container for disposal. Take care not to raise dust.

Waste Disposal Method: Solids: Sell as scrap for reuse. Dust, etc: In accordance with Local, State and Federal Waste Disposal Regulations.



VIII. SPECIAL PROTECTION INFORMATION


Respiratory Protection: If fumes, misting or dust condition occurs and TLV as indicated in Section II is exceeded, provide NIOSH approved respirators.

Ventilation Requirements: General exhaust is recommended (to keep airborne concentration of dust and fumes below ACGIH-TLV's). Use local exhaust as required.

Eye Protection: Recommended approved safety glasses or goggles when working with dusty material.

Protective Gloves: As required

Other Clothing or Equipment: As required



IX. SPECIAL PRECAUTIONS


Precautions to be Taken in Handling and Storage: No special precautions necessary for material in solid form. Material in powdered form should be stored in a tightly sealed container in a cool, dry area. Wash thoroughly after handling.


Work Practices: Use good housekeeping practices to prevent accumulations of dusts and to keep airborne dust concentrations at a minimum. This material is potentially contaminated with coatings such as oils for preservatives and other contaminants. If the material is contaminated, special precautions (such as process control and personal protective equipment appropriate to the nature of the suspected contaminants) should be taken to avoid resulting exposures when handling, cutting (thermal or mechanical) and/or heating or melting.


DOT Regulations:

Solid Forms:

Hazard Class:                   None

Powder:

Hazard Class:                   4.1

Identification Number:    UN3089

Packing Group:                III

Proper Shipping Name:   Metal powder, flammable, n.o.s. (Monel)



While the information set forth on this Material Safety Data Sheet is believed to be accurate, ESPI makes no representations regarding the accuracy or completeness of the information and assumes no liability for any loss, damage, or injury of any kind which may result from or arise out of the use or reliance on the information by any person.




Issued by:            S. Dierks

Date:                    February 2007