ELECTRONIC SPACE PRODUCTS INTERNATIONAL
1050 Benson Way, Ashland, OR 97520
Toll Free (800) 638-2581 * Fax (541) 488-8313
E-Mail: sales@espimetals.com
MATERIAL SAFETY DATA SHEET
I PRODUCT IDENTIFICATION
Trade Name: Aluminum Oxide Formula: Al203
Chemical Family: Metal oxide CAS #: 1344-28-1
Synonyms: Alumina
II HAZARDOUS INGREDIENTS
Hazardous Component % OSHA/PEL ACGIH/TLV Sec. 302 Sec. 304 Sec. 313
Aluminum Oxide 0-100 5 mg/m3 10 mg/m3 No No Yes
HMIS Ratings: Health: 1 Flammability: 0 Reactivity: 0 Protective Equipment: E: glasses, gloves, dust respirator
III PHYSICAL DATA
Boiling Point: 2977 oC Melting Point: 2050 oC
Specific Gravity: 4 g/cc Vapor Density: N/A
% Volatiles: N/E or N/A Solubility in H2O: Insoluble
Appearance and Odor: White powder or tablets, no odor
IV FIRE AND EXPLOSION HAZARDS DATA
Flash Point: N/E or N/A Method Used: Non-combustible
Explosive Limits: Upper: N/A Lower: N/A
Extinguishing Media: Use suitable extinguishing media for surrounding materials and type of fire.
Special Firefighting Procedures: Firefighters must wear full face, self-contained breathing apparatus with full protective clothing to prevent contact with skin and eyes. Fumes from fire are hazardous. Isolate runoff to prevent environmental pollution.
Unusual Fire & Explosion Hazards: Aluminum oxide may have an exothermic reaction, above 200 oC, with halocarbon vapors and may produce toxic hydrochloric acid and phosgene.
V HEALTH HAZARD INFORMATION
Effects of Exposure:
Aluminum compounds have many commercial uses and are commonly found in industry. Many of these materials are active chemically and thus exhibit dangerous toxic and reactive properties. Inhalation of fine aluminum oxide particles is associated with shaver's disease. (Sax, Dangerous Properties of Industrial Materials, eighth edition)
Route(s) of Entry: Inhalation.
Target Organs: May affect the lungs
Medical Conditions Generally Aggravated by Overexposure: Pre-existing respiratory disorders.
Acute Effects:
Inhalation: Toxic by inhalation of dust. Inhalation of finely divided dust may cause coughing, mucous production and shortness of breath.
Ingestion: No acute health effects recorded.
Skin: No acute health effects recorded.
Eye: Dust may cause eye irritation.
Chronic Effects: Inhalation: Inhalation of finely divided dust may cause lung damage affecting breathing capacity. No other chronic health effects recorded.
Carcinogenicity: NTP: No IARC: No OSHA: No
EMERGENCY AND FIRST AID PROCEDURES:
INHALATION: Remove to fresh air; keep warm and quiet; give oxygen if breathing is difficult and seek medical attention.
INGESTION: Give 1-2 glasses of milk or water and induce vomiting; seek medical attention. Never induce vomiting or give anything by mouth to an unconscious person.
SKIN: Remove contaminated clothing; brush material off skin; wash affected area with mild soap and water; seek medical attention.
EYES: Flush eyes with lukewarm water, lifting upper and lower eyelids, for at least 15 minutes. Seek medical attention.
VI REACTIVITY DATA
Stability: Stable
Conditions to Avoid: Not applicable
Incompatibility (Material to Avoid): Chlorine trifluoride, ethylene oxide, halocarbons, oxygen difluoride, sodium nitrate and vinyl acetate.
Hazardous Decomposition Products: Aluminum, hydrochloric acid and phosgene.
Hazardous Polymerization: Will not occur
VII SPILL OR LEAK PROCEDURES
Steps to be Taken in Case Material is Released or Spilled: Wear appropriate respiratory and protective equipment specified in section VIII. Isolate spill area and provide ventilation. Vacuum up spill using a high efficiency particulate absolute (HEPA) air filter and place in a closed container for proper disposal. Take care not to raise dust.
Waste Disposal Method: Dispose of in accordance with Local, State and Federal Waste Disposal Regulations.
VIII SPECIAL PROTECTION INFORMATION
Respiratory Protection: NIOSH/MSHA approved dust respirator if ventilation controls are not possible or are inadequate.
Ventilation: Use local exhaust to maintain concentration at or below the PEL. General exhaust is not recommended.
Protective Gloves: Rubber gloves
Eye Protection: Safety glasses
Other Protective Clothing or Equipment: Protective gear not necessary for aluminum oxide.
IX SPECIAL PRECAUTIONS
Precautions to Be Taken in Handling and Storing: Store in tightly sealed containers. Store in a cool, dry area. Wash thoroughly after handling.
Other Precautions: None
Work Practices: Implement engineering and work practice controls to reduce and maintain concentration of exposure at low levels. Use good housekeeping and sanitation practices. Do not use tobacco or food in work area. Wash thoroughly before eating and smoking. Do not blow dust off clothing or skin with compressed air. Maintain eyewash capable of sustained flushing, safety drench shower and facilities for washing.
The above information is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide. ESPI shall not be held liable for any damage resulting from handling or from contact with the above product.
Issued by: S. Dierks
Date: June 2005