SAFETY DATA SHEET

1   PRODUCT AND SUPPLIER IDENTIFICATION

Product Name:    Monel^® - foil, sheet, rod, wire, pellets

Other:                  Nickel Alloy 400, K500

Supplier:             ESPI Metals

                            1050 Benson Way

                            Ashland, OR 97520

Telephone:          800-638-2581

Fax:                     541-488-8313

Email:                  This email address is being protected from spambots. You need JavaScript enabled to view it.

Emergency:         Infotrac 800-535-5053 (US) or 352-323-3500 (24 hour)

Recommended Uses:   Scientific Research

2   HAZARDS IDENTIFICATION 

GHS Classification (29 CFR 1910.1200):   Not classified as hazardous

GHS Label Elements:

Signal Word: N/A

Hazard Statements: N/A

Precautionary Statements:   N/A

3   COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient:        CAS#:                %:               EC#:

Nickel                  7440-02-0         60-70            231-111-4

Copper                7440-50-8         30-40            231-159-6

Aluminum             7429-90-5          1-4              231-072-3

Iron                     7439-89-6          1-3              231-096-4

Manganese           7439-96-5          1-2              231-105-1

4   FIRST AID MEASURES

General Measures: Under normal handling and use, exposure to solid forms of this material present few health hazards. Subsequent operations such as grinding, melting or welding may produce potentially hazardous dust or fumes which can be inhaled or come in contact with the skin or eyes.

INHALATION: Remove to fresh air, keep warm and quiet, give oxygen if breathing is difficult. Seek medical attention.

INGESTION: Rinse mouth with water. Do not induce vomiting. Seek medical attention. Never induce vomiting or give anything by mouth to an unconscious person.

SKIN: Remove contaminated clothing, brush material off skin, wash affected area with soap and water. Seek medical attention if symptoms persist.

EYES: Flush eyes with lukewarm water, including under upper and lower eyelids, for at least 15 minutes. Seek medical attention if symptoms persist.

Most Important Symptoms/Effects, Acute and Delayed: May cause irritation. See section 11 for more information.

Indication of Immediate Medical Attention and Special Treatment: No other relevant information available.

5   FIREFIGHTING MEASURES

Extinguishing Media: Use suitable extinguishing media for surrounding material and type of fire.

Unsuitable Extinguishing Media: No information available.

Specific Hazards Arising from the Material: This product does not present fire or explosion hazards as shipped. Small chips, fine turnings and dust from processing may be ignitable. May emit metal oxide fumes under fire conditions.

Special Protective Equipment and Precautions for Firefighters: Full face, self-contained breathing apparatus and full protective clothing when necessary.

6   ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment, and Emergency Procedures: Wear appropriate respiratory and protective equipment specified in section 8. Avoid dust formation. Avoid contact with skin and eyes. Avoid breathing dust or fume.

Methods and Materials for Containment and Cleaning Up: Sweep or scoop up. Place in a closed container for further handling and disposal. Scrap can be collected for recycling.

Environmental Precautions: Do not allow to enter drains or to be released to the environment.

7 HANDLING AND STORAGE

Precautions for Safe Handling: Avoid creating dust. Provide adequate ventilation if dusts are created. See section 8 for information on personal protection equipment.

Conditions for Safe Storage: Store in a sealed container. Store in a cool, dry area. See section 10 for more information on incompatible materials.

8   EXPOSURE CONTROLS AND PERSONAL PROTECTION

Exposure Limits:   OSHA/PEL:                               ACGIH/TLV:

Nickel                      1 mg/m³                                   1.5 mg/m³

Copper                    0.1 mg/m³                                 0.2 mg/m³

Aluminum                 5 mg/m³ (respirable)                 1 mg/m³ (respirable)

Iron                         No exposure limit established      No exposure limit established

Manganese               5 mg/m³                                   0.2 mg/m³

Engineering Controls: Ensure adequate ventilation to maintain exposures below occupational limits. Whenever possible the use of local exhaust ventilation or other engineering controls is the preferred method of controlling exposure to airborne dust and fume to meet established occupational exposure limits. Use good housekeeping and sanitation practices. Do not use tobacco or food in work area. Wash thoroughly before eating or smoking. Do not blow dust off clothing or skin with compressed air.

Respiratory Protection: If permissible levels are exceeded, use NIOSH approved dust respirator.

Eye Protection: Safety glasses

Skin Protection: Not normally needed. Wear impermeable gloves, protective work clothing as necessary.

9   PHYSICAL AND CHEMICAL PROPERTIES

Appearance:

Form:                    Solid in various forms

Color:                    Gray metallic

Odor:                     Odorless

Odor Threshold:    Not determined

pH:                                             N/A

Melting Point:                            ~1300 ^oC - 1350 ^oC

Boiling Point:                             No data

Flash Point:                               N/A

Evaporation Rate:                     N/A

Flammability:                            No data

Upper Flammable Limit:            No data

Lower Flammable Limit:            No data

Vapor Pressure:                         No data

Vapor Density:                           N/A

Relative Density (Specific Gravity):     ~8.8 g/cc

Solubility in H₂O:                         Insoluble

Partition Coefficient (n-octanol/water):   Not determined

Autoignition Temperature:         No data

Decomposition Temperature:     No data

Viscosity:                                     N/A

10   STABILITY AND REACTIVITY

Reactivity: No data

Chemical Stability: Stable under recommended storage conditions.

Possibility of Hazardous Reactions: No data

Conditions to Avoid: Avoid creating or accumulating fines or dusts.

Incompatible Materials: Acids

Hazardous Decomposition Products: Metal oxide fume.

11   TOXICOLOGICAL INFORMATION

Likely Routes of Exposure: Inhalation, skin, eyes. Product as shipped does not present an inhalation hazard; however subsequent operations may create dusts or fumes which could be inhaled.

Symptoms of Exposure: Fines/dusts may irritate skin and eyes.

Acute and Chronic Effects:

Nickel: The most common harmful health effect of metallic nickel in humans is an allergic skin reaction in those who are sensitive to nickel. Although nickel compounds are known human carcinogens, the evidence suggests that the relatively insoluble metallic nickel is less likely to present a carcinogenic hazard than are the nickel compounds that tend to release proportionately more nickel ion.

Copper: Copper is a trace element that is essential for human health. Chronic exposure to copper dust can irritate the respiratory tract, nose, mouth and eyes, and cause headaches, dizziness, nausea and diarrhea. Ingestion of excessive amounts of copper may cause gastrointestinal distress. Chronic ingestion may damage the liver and kidneys.

Aluminum: There is strong evidence that aluminum (compounds) can cause irritation following exposure via either inhalation or injection. Modest evidence of an effect exists for reproductive toxicity following oral exposure, for neurological toxicity following either oral or injection exposure, and for bone toxicity following injection exposure. All other effects were judged to be supported by either limited evidence or no clear evidence at all.¹

Iron: Irritating to the respiratory tract, iron compounds may cause pulmonary fibrosis if dusts are inhaled. Inhalation of large amounts may cause iron pneumoconiosis. Chronic inhalation of finely divided powder may cause chronic iron poisoning and pathological deposition of iron in the body tissue. Ingestion may cause vomiting, diarrhea, pink urine, black stool, and liver damage. Iron compounds may also cause damage to the kidneys.

Manganese: Chronic inhalation exposure of humans to high levels of manganese may result in a syndrome called manganism which typically begins with feelings of weakness and lethargy and progresses to other symptoms such as gait disturbances, clumsiness, tremors, speech disturbances, a mask-like facial expression and psychological disturbances. Manganese is an essential micronutrient in humans.

Acute Toxicity: No data

Carcinogenicity: Nickel: NTP: R - reasonably anticipated to be a human carcinogen   IARC: 2B - possibly carcinogenic to humans

To the best of our knowledge the chemical, physical and toxicological characteristics of the substance are not fully known.

12   ECOLOGICAL INFORMATION

Ecotoxicity: No data

Persistence and Degradability: No data

Bioaccumulative Potential: No data

Mobility in Soil: No data

Other Adverse Effects: No further relevant information available.

13   DISPOSAL CONSIDERATIONS

Waste Disposal Method:

Product: Dispose of in accordance with Federal, State and Local regulations.

Packaging: Dispose of in accordance with Federal, State and Local regulations.

14   TRANSPORT INFORMATION

DOT/ADR/IATA/IMDG Regulations: Not regulated

UN Number:                            N/A

UN Proper Shipping Name:    N/A

Transport Hazard Class:        N/A

Packing Group:                       N/A

Marine Pollutant: No

Special Precautions: N/A

15   REGULATORY INFORMATION

TSCA Listed: All components are listed.

Regulation (EC) No 1272/2008 (CLP): N/A

Canada WHMIS Classification (CPR, SOR/88-66): N/A

HMIS Ratings: Health: 0     Flammability: 0     Reactivity: 0

NFPA Ratings: Health: 0     Flammability: 0      Reactivity: 0

Chemical Safety Assessment: A chemical safety assessment has not been carried out.

16   OTHER INFORMATION

Monel^® is a trademark of the Special Metals Corporation group of companies.

¹Krewski et al. (2007) Human Health Risk Assessment for Aluminum, Aluminum Oxide, and Aluminum Hydroxide, http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2782734/

The above information is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide. ESPI Metals shall not be held liable for any damages resulting from handling or from contact with the above product.

Prepared by:             ESPI Metals

Revised/Reviewed:   December 2014