Cadmium Powder

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SAFETY DATA SHEET

 

 

1   PRODUCT AND SUPPLIER IDENTIFICATION

Product Name:    Cadmium Powder

Formula:              Cd

Supplier:              ESPI Metals

                            1050 Benson Way

                            Ashland, OR 97520

Telephone:          800-638-2581

Fax:                     541-488-8313

Email:                  This email address is being protected from spambots. You need JavaScript enabled to view it.

Emergency:         Infotrac 800-535-5053 (US) or 352-323-3500 (24 hour)

Recommended Uses:  Scientific Research

 

 

2   HAZARDS IDENTIFICATION

GHS Classification (29 CFR 1910.1200):  Acute toxicity - oral, category 3, Acute toxicity - inhalation, category 1, Carcinogenicity, category 1B, Specific target organ toxicity - repeated exposure, category 2.

GHS Label Elements:

    

Signal Word: Danger

Hazard Statements:  H301 Toxic if swallowed, H330 Fatal if inhaled, H350 May cause cancer, H373 May cause damage to kidneys through prolonged or repeated exposure.

Precautionary Statements:  P201 Obtain special instructions before use, P202 Do not handle until all safety precautions have been read and understood, P260 Do not breath dust or fume, P264 Wash skin thoroughly after handling, P270 Do not eat, drink or smoke when using this product, P271 Use only outdoors or in a well-ventilated area, P281 Use personal protective equipment as required, P284 Wear respiratory protection, P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician, P330 Rinse mouth, P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing, P310 Immediately call a POISON CENTER or doctor/physician, P308+P313 IF exposed or concerned: Get medical advice/attention, P314 Get medical advice/attention if you feel unwell, P405 Store locked up, P501 Dispose of contents/container in accordance with local, state or federal regulations.

 

 

3   COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient:         Cadmium

CAS#:                  7440-43-9

%:                       100

EC#:                    231-152-8

 

 

4   FIRST AID MEASURES

General Measures: Emergency responders should take care to avoid secondary exposure to cadmium particulate. Wear appropriate protective equipment.

INHALATION: Remove to fresh air, keep warm and quiet, give oxygen if breathing is difficult. Seek immediate medical attention. Treat pulmonary edema as a priority, even if no symptoms (i.e. wheezing, coughing, shortness of breath, etc.) are apparent. Symptoms of pulmonary edema can be delayed up to 48 hours after exposure. Quickly transport victim to an emergency care facility.

INGESTION: Rinse mouth with water. Do not induce vomiting. Seek immediate medical attention. Never induce vomiting or give anything by mouth to an unconscious person. Ingested cadmium may lead to spontaneous vomiting. If vomiting occurs naturally, have victim rinse mouth with water again.

SKIN: Remove contaminated clothing, wash affected area with soap and water. Seek medical attention. Wash contaminated clothing before reusing.

EYES: Flush eyes with lukewarm water, including under upper and lower eyelids, for at least 15 minutes. Seek medical attention.

Most Important Symptoms/Effects, Acute and Delayed: May cause irritation. See section 11 for more information.

Indication of Immediate Medical Attention and Special Treatment: No other relevant information available.

 

 

5   FIREFIGHTING MEASURES

Extinguishing Media: Use Class D or other metal extinguishing agent.

Unsuitable Extinguishing Media: Do not use water or foam.

Specific Hazards Arising from the Material: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source, is a possible dust explosion hazard. May emit highly toxic fumes of cadmium oxide under fire conditions.

Special Protective Equipment and Precautions for Firefighters: Full face, self-contained breathing apparatus and full protective clothing to prevent contact with skin and eyes.

 

 

6   ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment, and Emergency Procedures: Establish a restricted entry zone based on the severity of the spill. Wear appropriate respiratory and protective equipment specified in section 8. Isolate spill area and provide ventilation. Avoid breathing dust or fume. Avoid contact with skin and eyes. Eliminate all sources of ignition.

Methods and Materials for Containment and Cleaning Up: Avoid creating dust. Cleanup spills with a vacuum system equipped with a HEPA filtration system and place in properly labeled closed containers. Special precautions must be taken when changing filters on HEPA vacuum cleaners used to clean up hazardous materials. Caution should be taken to minimize airborne generation of particulate and avoid contamination of air and water. Use only non-sparking tools.

Environmental Precautions: Do not allow to enter drains or to be released to the environment.

 

 

7   HANDLING AND STORAGE

Precautions for Safe Handling: Transfer material in closed systems or within a completely hooded containment with local exhaust ventilation. Avoid exposure to high temperature. Prevent spillage. Avoid creating dusts. Avoid breathing dust or fumes. Avoid contact with skin and eyes. Wash thoroughly before eating or smoking. See section 8 for information on personal protection equipment.

Conditions for Safe Storage, Including Any Incompatibilities: Store in a sealed container. Store in a cool, dry area. Storage containers should be labeled to indicate their contents. Do not store together with oxidizers, acids or halogens. See section 10 for more information on incompatible materials.

 

 

8   EXPOSURE CONTROLS AND PERSONAL PROTECTION

Exposure Limits:     Cadmium

OSHA/PEL:               0.005 mg/m3

ACGIH/TLV:             0.01 mg/m3

Appropriate Engineering Controls: Whenever possible the use of local exhaust ventilation or other engineering controls is the preferred method of controlling exposure to airborne dust and fume to meet established occupational exposure limits. Use vacuum for particulate removal from surfaces. Use vacuum cleaners with high efficiency particulate air (HEPA) filters. Do not use compressed air, brooms, or conventional vacuum cleaners to remove particulate from surfaces as this activity can result in elevated exposures to airborne particulate. Follow the manufacturer’s instructions when performing maintenance on HEPA filtered vacuums used to clean hazardous materials. Do not use tobacco or food in work area. Wash thoroughly before eating or smoking. Do not blow dust off clothing or skin with compressed air. Clothing worn in areas of exposure to cadmium dust or fume should be restricted to the workplace and laundered regularly.

Individual Protection Measures, Such as Personal Protective Equipment:

Respiratory Protection: When potential exposures are above the occupational limits, approved respirators must be used. Exposure to unknown concentrations of fumes or dusts requires the wearing of a pressure-demand self-contained breathing apparatus.

Eye Protection: Safety glasses or goggles

Skin Protection: Wear impermeable gloves, protective work clothing. Protective overgarments or work clothing must be worn by persons who may become contaminated with particulate during work activities.

 

 

9   PHYSICAL AND CHEMICAL PROPERTIES

Appearance:

Form:                    Powder

Color:                    Gray

Odor:                     Not determined

Odor Threshold:   Not determined

pH:                                              N/A

Melting Point:                             320.9 oC

Boiling Point:                              765 oC

Flash Point:                                N/A

Evaporation Rate:                       N/A

Flammability:                             No data

Upper Flammable Limit:             No data

Lower Flammable Limit:             No data

Vapor Pressure:                          1 mm Hg @ 394 oC

Vapor Density:                             N/A

Relative Density (Specific Gravity):     8.642 g/cc

Solubility in H2O:                        Insoluble

Partition Coefficient (n-octanol/water):   Not determined

Autoignition Temperature:         No data

Decomposition Temperature:     No data

Viscosity:                                     N/A

 

 

10   STABILITY AND REACTIVITY

Reactivity: No data

Chemical Stability: Stable under recommended storage conditions.

Possibility of Hazardous Reactions: High temperatures will generate toxic cadmium oxide fumes. Finely-divided metallic dust or powder is a moderate fire hazard and moderate explosion hazard when dispersed in air at high concentrations and exposed to heat, flame or other ignition sources.

Conditions to Avoid: Heat, sparks, flame. Dusting conditions.

Incompatible Materials: Peroxides, chlorates, nitrates, halogens, interhalogens, strong acids, strong bases, sulphur, potassium, zinc, selenium and tellurium.

Hazardous Decomposition Products: Cadmium oxides.

 

 

11   TOXICOLOGICAL INFORMATION

Likely Routes of Exposure: Inhalation, skin and eyes.

Symptoms of Exposure: Inhalation of fumes may cause upper respiratory tract irritation and systemic poisoning with early symptoms including headache, coughing, and a metallic taste.

Acute and Chronic Effects: After a delay of several hours (up to 10) after inhalation of dust or fumes, a person may develop constriction of the chest, persistent cough, and progressive shortness of breath. There may be headache, chills, diarrhea, muscle aches, nausea, vomiting, irritability, and restlessness. Prolonged exposure to cadmium dust and/or fume may cause loss of sense of smell, occasional ulcerations of the nasal passages, rhinolaryngitis, cough, shortness of breath, mild anemia, sleeplessness, irritability, loss of appetite, and cadmium-yellow fringe on teeth. The primary target organ for chronic cadmium effects is the kidney with increased excretion of a specific low molecular weight protein (beta-2-microglobulin). Exposures to high levels of cadmium dust or fume may be immediately dangerous to life or health and can cause delayed pneumonitis with fever and chest pain, and pulmonary edema resulting in death.

Acute Toxicity: LD50 oral - rat - 225mg/kg, LC50 inhalation - rat - 25mg/kg/30 min

Carcinogenicity: NTP: K - Known to be carcinogenic   IARC: 1 - Carcinogenic to humans

To the best of our knowledge the chemical, physical and toxicological characteristics of the substance are not fully known.

 

 

12   ECOLOGICAL INFORMATION

Ecotoxicity: No data

Persistence and Degradability: No data

Bioaccumulative Potential: No data

Mobility in Soil: No data

Other Adverse Effects: May be toxic to aquatic organisms. Do not allow material to be released to the environment. No further relevant information available.

 

 

13   DISPOSAL CONSIDERATIONS

Waste Disposal Method:

Product: Dispose of in accordance with Federal, State and Local regulations.

Packaging: Dispose of in accordance with Federal, State and Local regulations.

 

 

14   TRANSPORT INFORMATION

UN Number:                           6.1

UN Proper Shipping Name:   Toxic solid, inorganic, n.o.s., (Cadmium powder)

Transport Hazard Class:       UN3288

Packing Group:                      III

Marine Pollutant:                   No

 

 

15   REGULATORY INFORMATION

TSCA Listed: All components are listed.

Regulation (EC) No 1272/2008 (CLP): Acute toxicity - oral, category 3, Acute toxicity - inhalation, category 1, Carcinogenicity, category 1B, Specific target organ toxicity - repeated exposure, category 2, Hazardous to the aquatic environment - acute hazard, category 1, Hazardous to the aquatic environment - chronic hazard, category 1.

Canada WHMIS Classification (CPR, SOR/88-66): Acute toxicity, Carcinogenicity, Specific target organ toxicity - repeated exposure.

HMIS Ratings: Health: 3*(chronic)     Flammability: 1     Physical: 0

NFPA Ratings: Health: 3     Flammability: 1     Instability: 0

Chemical Safety Assessment: A chemical safety assessment has not been carried out.

 

 

16   OTHER INFORMATION

The information contained in this document is based on the state of our knowledge at the time of publication and is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide. ESPI Metals makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. ESPI Metals shall not be held liable for any damages resulting from handling or from contact with the above product. Users should satisfy themselves that they have all current data relevant to their particular use.

 

Prepared by:             ESPI Metals

Revised/Reviewed:   July 2015

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