MATERIAL SAFETY DATA SHEET

I.   PRODUCT IDENTIFICATION

Manufacturer/Supplier: 

ESPI Metals

1050 Benson Way, Ashland, OR 97520

Toll Free (800) 638-2581 * Fax (541) 488-8313

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Product Name:     Vanadium Oxide

Formula:              V₆O₁₃

CAS Number:       12037-42-2

II.   HAZARDOUS INGREDIENTS

Hazardous Component:    Vanadium Oxide V₆O₁₃

Percent (%):                     0-100

OSHA/PEL:                         N/E

ACGIH/TLV:                        N/E

III.   PHYSICAL DATA

Boiling Point:                   N/E

Melting Point:                  1500 ^oC

Specific Gravity:              3.36 g/cc

Solubility in H₂O:             Insoluble

Appearance and Odor:    Blue-black crystalline powder, no odor.

IV.   FIRE AND EXPLOSION HAZARDS DATA

Flash Point:  N/A

Autoignition Temperature:  N/A

Flammable Limits:  Lower:  N/A      Upper:  N/A

Extinguishing Media:  Use extinguishing media suitable for surrounding material and type of fire.

Special Fire Fighting Procedures:  Firefighters must wear full face, self-contained breathing apparatus and full protective clothing to prevent contact with skin and eyes.

Unusual Fire and Explosion Hazard:  When heated to decomposition vanadium oxide may emit toxic fumes.

V.   HEALTH HAZARD INFORMATION

Effects of Exposure:

To the best of our knowledge the chemical, physical and toxicological properties of vanadium oxide have not been thoroughly investigated and recorded.

Vanadium compounds act chiefly as an irritant to the conjunctiva and respiratory tract.  Exposure may cause conjunctivitis, rhinitis, and reversible irritation of the respiratory tract.  More severe cases may cause bronchitis, bronchospasms and asthma-like disease.  May cause polycythemia, red blood cell destruction and anemia, albuminuria and hematuria, gastrointestinal disorders, nervous complaints and severe cough.

Acute Effects:

Inhalation:  Breathing dust and fumes can irritate the respiratory tract and cause chest tightness, wheezing, and coughing.

Ingestion:  May cause gastrointestinal irritation.

Skin:  Contact may cause local irritation with reddening and itching.

Eye:  May cause moderate to severe eye irritation.

Chronic Effects:

Inhalation: Vanadium compounds may cause pneumonia and other pathologic symptoms.

Ingestion:  No data

Skin:  May cause dermatitis.

Eye:  May cause conjunctivitis.

Target Organs:  Kidneys, respiratory system, skin, eyes.

Medical Conditions Generally Aggravated by Exposure:  Pre-existing respiratory disorders.

Carcinogenicity:  NTP:  No      IARC:  No    OSHA:  No

EMERGENCY AND FIRST AID PROCEDURES:

INHALATION:  Remove victim to fresh air, keep warm and quiet, give oxygen if breathing is difficult and seek medical attention.

INGESTION:  Give 1-2 glasses of milk or water and induce vomiting, seek medical attention if symptoms persist.  Never induce vomiting or give anything by mouth to an unconscious person.

SKIN:  Remove contaminated clothing, brush material off skin, wash affected area with mild soap and water.  Seek medical attention if symptoms persist.

EYES:  Flush with lukewarm water, lifting upper and lower eyelids, for at least 15 minutes.  Seek medical attention if symptoms persist.

VI.   REACTIVITY DATA

Stability:  Stable

Conditions to Avoid:  None

Incompatibility (Materials to Avoid):  None recorded.

Hazardous Decomposition Products:  Vanadium oxide fume

Hazardous Polymerization:  Will not occur

VII.   SPILL OR LEAK PROCEDURES

Steps to Be Taken in Case Material Is Released or Spilled:  Wear appropriate respiratory and protective equipment specified in section VIII.  Isolate spill area and provide ventilation.  Scoop up or vacuum up spill using a high efficiency particulate absolute (HEPA) air filter and place in a closed container for proper disposal.  Take care not to raise dust.

Waste Disposal Method:  Dispose of in accordance with Federal, State and Local regulations.

VIII.   SPECIAL PROTECTION INFORMATION

Respiratory Protection:  NIOSH-approved respirator.

Ventilation:  Provide sufficient ventilation to keep exposure to dust below permissible exposure limits.

Eye Protection:  Safety goggles

Protective Gloves:  Impervious gloves

Other Protective Clothing and Equipment:  Body protection as necessary to prevent skin contact.

IX.   SPECIAL PRECAUTIONS

Other Handling and Storage Conditions:  Keep container tightly closed. Store in a cool, dry, well-ventilated area.  Open and handle container with care.  Wash thoroughly after use.  Do not get in eyes, on skin, or clothing.  Do not breath dust, vapor, mist, gas.

Work Practices:  Implement engineering and work practice controls to reduce and maintain concentration of exposure at low levels.  Use good housekeeping and sanitation practices.  Do not use tobacco or food in work area.  Wash thoroughly before eating and smoking.  Do not blow dust off clothing or skin with compressed air.  Maintain eyewash capable of sustained flushing, safety drench shower, and facilities for washing.

Warning:  Irritates eyes and lungs.

TSCA Listed:  Yes

DOT Regulations:

   Hazard Class:                    6.1

   Identification Number:     UN3285

   Packing Group:                  II

   Proper Shipping Name:     Vanadium compound, n.o.s., (vanadium oxide)

The above information is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide.  ESPI shall not be held liable for any damages resulting from handling or from contact with the above product.

Issued by:                S. Dierks

Revised/Verified:       August 2011