MATERIAL SAFETY DATA SHEET

I.   PRODUCT IDENTIFICATION

Manufacturer/Supplier:

ESPI Metals

1050 Benson Way, Ashland, OR 97520

Toll Free (800) 638-2581 * Fax (541) 488-8313

E-Mail: This e-mail address is being protected from spambots. You need JavaScript enabled to view it

Trade Name:      Titanium Fluoride

Formula:             TiF₃

CAS Number:      13470-08-1

II.   HAZARDOUS INGREDIENTS

Components Hazardous:  Titanium Fluoride

Percent (%):  98

III.   PHYSICAL DATA

Boiling Point:                  1400 ^oC

Melting Point:                 1200 ^oC

Specific Gravity:            3.4

Solubility in H₂O:            Sparingly soluble

Appearance and Odor:   Violet to purple-red

IV.   FIRE AND EXPLOSION HAZARDS DATA

Flash Point (Method Used):  None

Autoignition Temperature:  N/A

Flammable Limits:  Upper:  N/A     Lower:  N/A

Extinguishing Media:  CO₂, Dry Powder, Water Spray

Special Fire Fighting Procedures:  N/A

Unusual Fire & Explosion:  N/A

V.   HEALTH HAZARD INFORMATION

Effects of Exposure:

Eye Effects:  Irritant

Skin Effects:  Irritant

Other Toxic Effects:  A very large dose or prolonged exposure may cause fluorosis (bone damage), and kidney or liver damage.  Inhalation of dust may cause irritation of the respiratory tract, pulmonary edema, congestion and fluorosis (bone damage).

Target Organ Toxin:  Eye, Skin, Kidney, Liver, Lung, Bone.

Permissible Exposure Limits:  ACGIH TLV for fluorides as F^-:  2.5 mg/m³.

EMERGENCY AND FIRST AID PROCEDURES:

EYES:  Flush with water for at least 15 minutes.  Seek medical attention.

SKIN:  Flush with water for at least 15 minutes.

INGESTION:  Dilute with milk, lime water or aluminum hydroxide.  Seek emergency medical attention immediately.  Treat with gentle lavage.  Multiple lumen tube suggested.  Monitor for cardiac arrhythmias.

INHALATION:  In case of respiratory difficulty, seek emergency medical attention.

VI.   REACTIVITY DATA

Stability:  Stable

Incompatibility (Material to Avoid):  Avoid contact with strong acids.

Hazardous Decomposition Thermal and Other:  Contact with acids may produce HF which is a highly toxic and corrosive material.  In the presence of moisture and heat it may generate HF fumes.

VII.   SPILL OR LEAK PROCEDURES

Steps to Be Taken in Case Material Is Released or Spilled:  Sweep or scoop up and remove.  Flush spill area with water.  Disposal should  be in accordance with all Local, State and Federal regulations.

Waste Disposal Method:  Dispose of with normal refuse.

VIII.   SPECIAL PROTECTION INFORMATION

Respiratory Protection (Specify Type):  Filter, dusts, fume, mists.

Ventilation:  Local Exhaust.  Use with adequate ventilation.

Protective Gloves:  Polyvinyl chloride, natural rubber, polyethylene.

Eye Protection:  Safety glasses

Other Protective Equipment:  N/A

IX.   SPECIAL PRECAUTIONS

Other Handling and Storage Considerations:

‚        Wash thoroughly after handling.

‚        Do not get in eyes, on skin or clothing.

‚        Do not breathe dust, vapor, mist, or gas.

‚        Contact with acid may release toxic vapors (HF) which causes burns.

The above information is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide.  ESPI shall not be held liable for any damage resulting from handling or from contact with the above product.

Prepared by:          S. Dierks

Dated:                   September 1994