MATERIAL SAFETY DATA SHEET

I.   PRODUCT IDENTIFICATION

Manufacturer/Supplier:

ESPI Metals

1050 Benson Way, Ashland, OR 97520

Toll Free (800) 638-2581 * Fax (541) 488-8313

E-Mail: This e-mail address is being protected from spambots. You need JavaScript enabled to view it

Product Name:     Strontium Nitride

Formula:              Sr₃N₂

CAS Number:       12033-82-8

II.   HAZARDOUS INGREDIENTS

Hazardous Component:  Strontium Nitride

Percent (%):                  0-100

OSHA/PEL:                     N/E

ACGIH/TLV:                    N/E

HMIS Ratings:

Health:                           1

Flammability:                1

Reactivity:                     1

III.   PHYSICAL DATA

Boiling Point:                   No data

Melting Point:                  No data

Specific Gravity:             No data

Solubility in H₂O:            Decomposes

Appearance and Odor:   Black crystalline solid, ammonia odor in moist air

IV.   FIRE AND EXPLOSION HAZARDS DATA

Flash Point:  N/A

Autoignition Temperature:  No Data

Flammable Limits:  Lower:  N/E       Upper:  N/E

Extinguishing Media:  DO NOT USE WATER.  Use extinguishing powder for metal fires.

Special Firefighting Procedures:  Firefighters must wear full face, self-contained breathing apparatus with full protective clothing to prevent contact with skin and eyes.

Unusual Fire and Explosion Hazards:  Generates ammonia on contact with moisture.

V.   HEALTH HAZARD INFORMATION

Effects of Exposure:

To the best of our knowledge the chemical, physical and toxicological properties of strontium nitride have not been thoroughly investigated and recorded.

Strontium compounds have a low order of toxicity.  It is chemically and biologically similar to calcium.  The oxides and hydroxides are moderately caustic materials (Sax, Dangerous Properties of Industrial Materials, eighth edition).

The details of the toxicity of nitrides as a group are unknown.  (Sax, Dangerous Properties of Industrial Materials, eighth edition)

Acute and Chronic Effects:

Inhalation:  No data.  As a corrosive material may cause mucous membrane and respiratory tract irritation

Ingestion:  As a corrosive material, ingestion will cause injury to the mouth, esophagus and gastrointestinal tract.

Skin:  Moderate irritation.  Prolonged skin contact can cause irritation, redness and possibly burns.

Eye:  May cause irritation and chemical burns.

Medical Conditions Generally Aggravated by Exposure:  Pre-existing lung disorders.

Carcinogenicity:  NTP:  No     IARC:  No   OSHA:  No

EMERGENCY AND FIRST AID PROCEDURES:  Remove from exposure.

INHALATION:  Remove victim to fresh air, keep warm and quiet, give oxygen if breathing is difficult.  Seek medical attention.

INGESTION:  Do not induce vomiting.  Seek immediate medical attention.

SKIN:  Remove any contaminated clothing.  Brush material off skin.  Wash affected area with mild soap and water.  Seek medical attention.

EYES:  Flush eyes with lukewarm water, lifting upper and lower eyelids, for at least 15 minutes.  Seek medical attention.

VI.   REACTIVITY DATA

Stability:   Unstable in moist conditions

Conditions to Avoid:  Moisture

Incompatibility (Materials to Avoid):  Water/moisture.

Hazardous Decomposition Products:  Strontium hydroxide, ammonia

Hazardous Polymerization:  Will not occur

VII.   SPILL OR LEAK PROCEDURES

Steps to Be Taken in Case Material Is Released or Spilled:  Wear appropriate respiratory and protective equipment specified in section VIII.  Isolate spill area, provide ventilation and extinguish sources of ignition.  Vacuum up spill using a high efficiency particulate absolute (HEPA) air filter and place in a closed container for proper disposal.  Take care not to raise dust.  Use non-sparking tools.

Waste Disposal Method:  Dispose of in accordance with applicable Federal, State and Local regulations.

VIII.   SPECIAL PROTECTION INFORMATION

Respiratory Protection:  Wear NIOSH-approved dust-mist-fume respirator for ordinary use.  Self-contained breathing apparatus for emergency use.

Ventilation:  Handle in a drybox to prevent contact with moisture.  Use local exhaust to maintain concentration below exposure levels.  General exhaust is not recommended.

Eye Protection:  OSHA approved safety goggles

Protective Gloves:  Impervious gloves

Other Protective Clothing or Equipment:  Lab coat and apron, flame and chemical resistant coveralls.

IX.   SPECIAL PRECAUTIONS

Precautions to Be Taken in Handling and Storage:  Store in tightly closed containers in a cool, dry place.  Wash hands and face throughly after handling and before meals.  Store in well ventilated area.

Precautionary Labeling:  Danger:  Corrosive, may cause irritation or burns.

Work Practices:  Implement engineering and work practice controls to reduce and maintain concentration of exposure at low levels.  Use good housekeeping and sanitation practices.  Do not use tobacco or food in work area.  Wash thoroughly before eating and smoking.  Do not blow dust off clothing or skin with compressed air.  Maintain eyewash capable of sustained flushing, safety drench shower and facilities for washing.

TSCA Listed:                    Yes

DOT Regulations:

Hazard Class:                  4.3

Identification Number:   UN2813

Packing Group:               II

Proper Shipping Name:  Water-reactive solid, n.o.s. (Strontium nitride)

The above information is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide.  ESPI shall not be held liable for any damage resulting from handling or from contact with the above product.

Issued by:                           S. Dierks

Revised/Verified:                  March 2010