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Barium

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SAFETY DATA SHEET

 

 

1   PRODUCT AND SUPPLIER IDENTIFICATION

Product Name:    Barium - rod, pieces, sheet

Formula:             Ba

 

Supplier:             ESPI Metals

                            1050 Benson Way

                            Ashland, OR 97520

Telephone:          800-638-2581

Fax:                     541-488-8313

Email:                  This e-mail address is being protected from spambots. You need JavaScript enabled to view it

Emergency:         Infotrac 800-535-5053 (US) or 352-323-3500 (24 hour)

Recommended Uses:   Scientific Research

 

 

2   HAZARDS IDENTIFICATION 

GHS Classification (29 CFR 1910.1200):   Water reactive, Category 2, Skin irritation, Category 2, Eye irritation, Category 2A

GHS Label Elements:

    

Signal Word: Danger

Hazard Statements: H261 In contact with water releases flammable gas, H315 Causes skin irritation, H319 Causes serious eye irritation, H335 May cause respiratory irritation.

Precautionary Statements: P231+P232 Handle under inert gas. Protect from moisture, P261 Avoid breathing dust/fume/gas/mist/vapors/spray, P305+P351+P338 IF IN EYES: rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing, P422 Store contents under inert gas.

 

 

3   COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient:         Barium

CAS#:                  7440-39-3

%:                       100

EC#:                     231-149-1

 

 

4   FIRST AID MEASURES

INHALATION: Remove to fresh air, keep warm and quiet, give oxygen if breathing is difficult. Seek immediate medical attention.

INGESTION: Quickly wipe material from mouth and rinse with water. Do not induce vomiting. Seek medical attention immediately.

SKIN: Remove contaminated clothing if necessary. Brush off any visible solids. Wash the affected area with water for at least 15 minutes. Seek medical attention.

EYES: Immediately flush eyes with copious amounts of water, including under eyelids for at least 10-15 minutes. A victim may need assistance in keeping their eyelids open. Seek immediate medical attention.

 

Most Important Symptoms/Effects, Acute and Delayed: May cause severe irritation in contact with mucous membranes and moist skin. See section 11 for more information.

Indication of Immediate Medical Attention and Special Treatment: No other relevant information available.

 

 

5   FIREFIGHTING MEASURES

Extinguishing Media: Use Class D dry powder extinguishing agent.

Unsuitable Extinguishing Media: Do not use water, carbon dioxide or halogenated extinguishers.

Specific Hazards Arising from the Material: Material readily reacts with water generating flammable hydrogen gas. May emit fumes of barium oxide under fire conditions.

Special Protective Equipment and Precautions for Firefighters: Full face, self-contained breathing apparatus and full protective clothing to prevent contact with skin and eyes. Barium metal can reignite after fire is initially extinguished. Never leave extinguished fire unattended.

 

 

6   ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment, and Emergency Procedures: Wear appropriate respiratory and protective equipment specified in section 8. Avoid contact with skin and eyes. Avoid breathing dust or fume. Eliminate all sources of ignition. Isolate spill area.

Methods and Materials for Containment and Cleaning Up: Sweep or scoop spilled product and place in a closed container for further handling and disposal. Do not use water for spill clean-up. Cover very small quantities in the open with powdered limestone and let decompose. Use only non-sparking tools and natural bristle brushes.

Environmental Precautions: Do not flush to sewer, stream, or other bodies of water. Do not allow to enter drains or to be released to the environment.

 

 

7   HANDLING AND STORAGE

Precautions for Safe Handling: Handle under dry protective gas such as argon. Use non-sparking tools. Protect from sources of ignition. Do not allow contact with water. Avoid contact with skin and eyes. Wash thoroughly before eating or smoking. See section 8 for information on personal protection equipment.

Conditions for Safe Storage, Including Any Incompatibilities: Barium metal should be stored in tightly-closed containers under argon or mineral oil. Keep away from sparks, heat and flame. Storage area should be free of combustibles and ignition sources. Do not store together with acids, oxidizers, halogens. Protect from water/moisture. See section 10 for more information on incompatible materials.

 

 

8   EXPOSURE CONTROLS AND PERSONAL PROTECTION

Exposure Limits:     Barium

OSHA/PEL:              0.5 mg/m3

ACGIH/TLV:             0.5 mg/m3

Appropriate Engineering Controls: Handle in a humidity controlled atmosphere. Handle in an enclosed, controlled process under dry argon. Whenever possible the use of local exhaust ventilation or other engineering controls is the preferred method of controlling exposure to airborne dust and fume to meet established occupational exposure limits. Do not use tobacco or food in work area. Wash thoroughly before eating or smoking. Do not blow dust off clothing or skin with compressed air. Prepare for the possibility of a fire. Keep extinguishing agents, tools for handling and protective clothing readily available.

Individual Protection Measures, Such as Personal Protective Equipment:

Respiratory Protection: Wear a NIOSH/MSHA approved respirator when high concentrations are present.

Eye Protection: Always wear approved chemical splash proof goggles.

Skin Protection: Rubber gloves, flame retardant protective work clothing.

 

 

9   PHYSICAL AND CHEMICAL PROPERTIES

Appearance:

Form:                   Solid in various forms

Color:                   Silver-gray metallic

Odor:                    Not determined

Odor Threshold:   Not determined

pH:                                              N/A

Melting Point:                             725 oC

Boiling Point:                              1640 oC

Flash Point:                                N/A

Evaporation Rate:                      N/A

Flammability:                             Flammable solid

Upper Flammable Limit:            No data

Lower Flammable Limit:            No data

Vapor Pressure:                         10 mm at 1049 oC

Vapor Density:                            N/A

Relative Density (Specific Gravity):     3.51 g/cc at 20 oC

Solubility in H2O:                        Decomposes

Partition Coefficient (n-octanol/water):   Not determined

Autoignition Temperature:         No data

Decomposition Temperature:     No data

Viscosity:                                     N/A

 

 

10   STABILITY AND REACTIVITY

Reactivity: No data

Chemical Stability: Stable under recommended storage conditions.

Possibility of Hazardous Reactions: Barium reacts readily with water releasing flammable hydrogen gas.

Conditions to Avoid: Heat, sparks, flame. Exposure to water or moist air.

Incompatible Materials: Water or moisture, oxidizing agents, oxygen, acids, alcohols, halocarbons, carbon dioxide, ammonia.

Hazardous Decomposition Products: Barium oxides, hydrogen gas.

 

 

11   TOXICOLOGICAL INFORMATION

Likely Routes of Exposure: Inhalation, skin, eyes. Product as shipped does not present an inhalation hazard; however subsequent operations may create dusts or fumes which could be inhaled.

Symptoms of Exposure: May cause severe irritation to the nose, throat, and upper respiratory tract, mouth, throat, and esophagus. Contact with skin can cause mild to moderate irritation. May cause chemical burns in eyes or on skin as it reacts with moisture on living tissue.

Acute and Chronic Effects: Barium compounds may cause severe gastroenteritis, including abdominal pain, vomiting and diarrhea, tremors, faintness, paralysis of the arms and legs, and slow or irregular heartbeat. Severe cases may produce collapse and death due to respiratory failure. Soluble barium compounds are more likely to cause these effects than insoluble compounds. Inhalation of fumes may cause sore throat, coughing, labored breathing, and irritation of the respiratory tract as well as the above symptoms. Chronic exposure to barium may cause sensitization, chronic barium poisoning, dermatitis, corneal opacity and blindness.

Acute Toxicity: No data

Carcinogenicity: NTP: Not identified as carcinogenic   IARC: Not identified as carcinogenic

To the best of our knowledge the chemical, physical and toxicological characteristics of the substance are not fully known.

 

 

12   ECOLOGICAL INFORMATION

Ecotoxicity: No data

Persistence and Degradability: No data

Bioaccumulative Potential: No data

Mobility in Soil: No data

Other Adverse Effects: Do not allow material to be released to the environment. No further relevant information available.

 

 

13   DISPOSAL CONSIDERATIONS

Waste Disposal Method:

Product: Dispose of in accordance with Federal, State and Local regulations.

Packaging: Dispose of in accordance with Federal, State and Local regulations.

 

 

14   TRANSPORT INFORMATION

DOT/ADR/IATA/IMDG Regulations:

UN Number:                           4.3

UN Proper Shipping Name:   Barium

Transport Hazard Class:       UN1400

Packing Group:                      II

Marine Pollutant: No

Special Precautions: Warning, substances which, in contact with water, emit flammable gases.

 

 

15   REGULATORY INFORMATION

TSCA Listed: All components are listed.

Regulation (EC) No 1272/2008 (CLP): Water reactive, Category 2, Skin irritation, Category 2, Eye irritation, Category 2A.

Canada WHMIS Classification (CPR, SOR/88-66): Class B, Division 6 - Reactive flammable material.

HMIS Ratings: Health: 2     Flammability: 3   Reactivity: 1

NFPA Ratings: Health: 2     Flammability: 3   Reactivity: 1   Special Hazard: W

Chemical Safety Assessment: A chemical safety assessment has not been carried out.

 

 

16   OTHER INFORMATION

The above information is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide. ESPI Metals shall not be held liable for any damages resulting from handling or from contact with the above product.

 

Prepared by:             ESPI Metals

Revised/Reviewed:   May 2014